Synthesis and self-assembly of carbamoylmethylphosphonate acrylamide-based diblock copolymers: new valuable thermosensitive materials.

نویسندگان

  • Fabrice Azemar
  • Donatien Gomes-Rodrigues
  • Jean-Jacques Robin
  • Sophie Monge
چکیده

We report the synthesis by RAFT polymerization of well-defined diblock copolymers bearing carbamoylmethylphosphonate moieties which proved to sorb gadolinium. These poly(diethyl-6-(acrylamido)hexylcarbamoylmethylphosphonate-b-acrylic acid) (P(CPAAm6C-b-AA)) copolymers were able to self-assemble as a function of temperature, above their cloud point value.

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عنوان ژورنال:
  • Dalton transactions

دوره 45 5  شماره 

صفحات  -

تاریخ انتشار 2016